Doesn't work like that - with MLO, one now has to reserve hostapd AID's for MLO based clients in case they may be a candidate for the connection across two radios.
And in my testing so far - MLO is a bit of a hot-mess...
1) What happens when the Client STA is in good RSSI for 2.4, but poor RSSI for 5GHz - this happens quite often
2) What happens with a Client STA in MLO mode roams in an ESS with multiple AP's - we can get into a situation where 2.4GHz is camped on AP1, and 5GHz radio wants to move to AP2 - this is now a problem as how do you manage the upper layers in the stack.
3) MLO only happens when the SSID and Security Creds are the same - if one has different SSID"s per band, then MLO isn't going to work.
WRT items 2 and 3 - common SSID across the AP's and Bands makes a lot of sense...
Going back to Item 1 - this is about resource management across radios - this would even occur on 2 radios in the same band...
The schedulers in the AP (and in the case of multiple AP's the WLC) need to take this all into consideration - imagine a cohort of clients that a mixed base of capabilities - some might in 802.11n with WPA2 in 2.4, some might be 802.11ax/be with all the good stuff - how to manage this across 32 to 50 clients per radio, and how much do one reserves for MLO in a high traffic environment - does was one reserve 20 percent perhaps for MLO candidates (and those are not real connections, just possible ones).
IN the current state of the art - we barely have schedulers that can handle UL/DO-MU, OFDMA...
As I mentioned earlier - it does seem like MLO is the 3D-TV feature of WiFi7...
And also consider the use case of a mobile phone - power is everything - why would one add an additional radio considering the the constraints above?
And of course, there's the business aspect - who is going to pay for all that testing across bands, including DFS channels in 5G, and the whole managed spectrum stuff in 6G - yeah - it's a mess...
And let's not talk about the regulatory testing cost, plus internal QA - yeah, that's a spendy amount...