Are you sure they are using a VPN solution to bypass your parental controls time schedule? If they are using wireless devices, they can get around your restrictions by doing something as simple as connecting to a different SSID or Wifi network in range that is NOT controlled by your router. That (very) effectively negates any settings you would apply on the AC3200.
The only thing you can do technologically in this situation is to activate parental restrictions on the devices themselves. Set up whatever limits the device supports and do not share the password with your kids under an circumstances. Then hope they don't reset their devices back to factory / OS defaults to remove your restrictions.
What you will find is that kids will research and uncover all manner of work-arounds to anything you attempt to put into place. Depending on their ages, in the end, your only real control is your ability to exact consequences for their actions after your expectations for their behavior have been clearly communicated. It's up to them to obey the rules of the household and up to you to enforce them in the way that suits the situation best. Relying on technology to do that for you will only get you so far.
Good luck!