My echo dot does not find my 5 ghz wifi network, only if I change a wifi setting on the router and the wifi channels change for a sec my echo dot sees the 5 Ghz and can connect.
Try moving the Dot further from the wireless router, which seems counterintuitive, but some client devices need more moderate RSSI for some reason an RF engineer may be able to explain.
Roaming Assistant also did not seem to help transition my phone across my AiMesh nodes, though I was seeing RA entries in the syslog.